Berichtigung: Light‐Induced Efficient Hydroxylation of Benzene to Phenol by Quinolinium and Polyoxovanadate‐Based Supramolecular Catalysts
نویسندگان
چکیده
منابع مشابه
Application of Response Surface Methodology as an Efficient Approach for Optimization of Operational Variables in Benzene Hydroxylation to Phenol by V/SBA-16 Nanoporous Catalyst
Herein, we prepared a V/SBA-16 catalyst using vanadyl acetylacetonate as a precursor and SBA-16 nanoporous silica as a support via an immobilization technique. The ordered mesoporous structure of catalyst was determined by X-ray diffraction and transmission electron microscopy techniques , and the catalyst was evaluated in the benzene hydroxylation to phenol with hydrogen peroxide (H2O2) as a ...
متن کاملSynthesis and characterization of copper(ii) complexes with multidentate ligands as catalysts for the direct hydroxylation of benzene to phenol.
Four copper(ii) complexes with multidentate ligands, ([CuL1Cl2]), ([Cu(HL2)Cl2]), ([Cu2(L2)2](ClO4)2) and ([CuL3(HOCH3)ClO4]) {L1 = N,N-bis((pyridin-2-yl)methyl) prop-2-yn-1-amine, HL2 = 2-((((1-methyl-1H-imidazol-2-yl)methyl)(pyridin-2-ylmethyl)amino)methyl)phenol and HL3 = 2-((((1-methyl-1H-imidazol-2-yl)methyl)(pyridin-2-ylmethyl)amino)methyl)-2-t-butyl-phenol} are reported. The complexes we...
متن کاملFacile Synthesis of Vanadium Oxide/Reduced Graphene Oxide Composite Catalysts for Enhanced Hydroxylation of Benzene to Phenol
The vanadium oxide/reduced graphene oxide (VOx/RGO) composites have been prepared by a simple solvothermal method with the assistance of cationic surfactant cetyltrimethylammonium bromide (CTAB). The microstructure and morphology of the resultant VOx/RGO composites have been well characterized. The VOx nanoparticles are highly dispersed on the RGO sheets with a particle size of about 25 nm. Whe...
متن کاملA hierarchical Fe/ZSM-5 zeolite with superior catalytic performance for benzene hydroxylation to phenol.
We report the one-step synthesis of a highly active hierarchical Fe/ZSM-5 zeolite catalyst with a strongly improved lifetime in the selective hydroxylation of benzene to phenol with nitrous oxide; compared to the best Fe/ZSM-5 catalyst, the turnover number after 24 h on stream is almost four times higher.
متن کاملHydroxylation of phenol to hydroquinone catalyzed by a human myeloperoxidase-superoxide complex: possible implications in benzene-induced myelotoxicity.
Benzene, a known human myelotoxin and leukemogen is metabolized by liver cytochrome P-450 monooxygenase to phenol. Further hydroxylation of phenol by cytochrome P-450 monooxygenase results in the formation of mainly hydroquinone, which accumulates in the bone marrow. Bone marrow contains high levels of myeloperoxidase. Here we report that phenol hydroxylation to hydroquinone is also catalyzed b...
متن کاملذخیره در منابع من
با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید
ژورنال
عنوان ژورنال: Angewandte Chemie
سال: 2021
ISSN: 0044-8249,1521-3757
DOI: 10.1002/ange.202105010